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Nuclear reactions and conservation laws

Learning objectives

  • Outcome

    Balance a nuclear reaction equation by applying the conservation of charge number ZZ and nucleon number AA.

  • Outcome

    Determine the unknown nuclide or particle in a reaction from the ZZ and AA balance.

  • Outcome

    Classify a reaction as alpha, beta, fission, or fusion and state the conservation laws that apply to it.

  • Outcome

    Calculate the energy released in a reaction from its mass defect using E=Δmc2E=\Delta m c^2.

Understand the idea

Nuclear Reactions and Conservation Laws

Text

A nuclear reaction is a process in which the composition of one or more nuclei changes: the reactants and products are different nuclides, written as ZAX^{A}_{Z}\mathrm{X}, where AA is the nucleon number and ZZ the charge (proton) number. Three bookkeeping rules always hold: the total charge number ZZ is conserved, the total nucleon number AA is conserved, and the total relativistic energy (rest mass plus kinetic energy) is conserved. Two more rules complete the picture: linear momentum is conserved in every collision and decay, and lepton number is conserved in beta processes. Because ZZ and AA must balance, they let you find an unknown product: count AA and ZZ on each side and solve for the missing entry. If the total rest mass of the products is smaller than that of the reactants, the difference Δm\Delta m appears as kinetic energy of the products through E=Δmc2E = \Delta m c^2, so the reaction releases energy.

Worked examples

Direct

Problem

Balance the fission reaction 92235U+01n→56141Ba+3692Kr+x 01n^{235}_{92}\mathrm{U} + ^{1}_{0}\mathrm{n} \to ^{141}_{56}\mathrm{Ba} + ^{92}_{36}\mathrm{Kr} + x\,^{1}_{0}\mathrm{n}: find xx and check both conservation laws.

Solution

Step 1 — nucleon number. Left side: 235+1=236235 + 1 = 236. Right side: 141+92+x=233+x141 + 92 + x = 233 + x. Conservation of AA gives 236=233+x236 = 233 + x, so x=3x = 3.

Step 2 — charge number. Left side: 92+0=9292 + 0 = 92. Right side: 56+36+3⋅0=9256 + 36 + 3 \cdot 0 = 92. The equality holds, so ZZ is conserved.

Answer: x=3x = 3, that is

92235U+01n→56141Ba+3692Kr+3 01n.^{235}_{92}\mathrm{U} + ^{1}_{0}\mathrm{n} \to ^{141}_{56}\mathrm{Ba} + ^{92}_{36}\mathrm{Kr} + 3\,^{1}_{0}\mathrm{n}.

Application

Problem

Find the unknown product in the reaction 1327Al+24He→1530P+ZAX^{27}_{13}\mathrm{Al} + ^{4}_{2}\mathrm{He} \to ^{30}_{15}\mathrm{P} + {}^{A}_{Z}\mathrm{X} and identify the particle.

Solution

Step 1 — nucleon number. 27+4=3127 + 4 = 31 and 30+A=3130 + A = 31, so A=1A = 1.

Step 2 — charge number. 13+2=1513 + 2 = 15 and 15+Z=1515 + Z = 15, so Z=0Z = 0.

Step 3 — identify. A nuclide with A=1A = 1 and Z=0Z = 0 is the neutron 01n^{1}_{0}\mathrm{n}.

Check. The full equation is

1327Al+24He→1530P+01n,^{27}_{13}\mathrm{Al} + ^{4}_{2}\mathrm{He} \to ^{30}_{15}\mathrm{P} + ^{1}_{0}\mathrm{n},

so this is an (α,n)(\alpha, n) reaction: an alpha particle is absorbed and a neutron is emitted.

Transfer

Problem

For the fusion reaction 12H+13H→24He+01n^{2}_{1}\mathrm{H} + ^{3}_{1}\mathrm{H} \to ^{4}_{2}\mathrm{He} + ^{1}_{0}\mathrm{n}, check the conservation laws and estimate the released energy. Rest masses: m(12H)=2.014102 um(^{2}_{1}\mathrm{H}) = 2.014102\ \mathrm{u}, m(13H)=3.016049 um(^{3}_{1}\mathrm{H}) = 3.016049\ \mathrm{u}, m(24He)=4.002603 um(^{4}_{2}\mathrm{He}) = 4.002603\ \mathrm{u}, m(01n)=1.008665 um(^{1}_{0}\mathrm{n}) = 1.008665\ \mathrm{u}; 1 u≈931.5 MeV/c21\ \mathrm{u} \approx 931.5\ \mathrm{MeV}/c^{2}.

Solution

Step 1 — conservation laws. For AA: 2+3=52 + 3 = 5 and 4+1=54 + 1 = 5. For ZZ: 1+1=21 + 1 = 2 and 2+0=22 + 0 = 2. Both are conserved, so the reaction is allowed; no leptons are involved, so lepton number needs no check.

Step 2 — total rest masses.
Reactants: 2.014102+3.016049=5.030151 u2.014102 + 3.016049 = 5.030151\ \mathrm{u}.
Products: 4.002603+1.008665=5.011268 u4.002603 + 1.008665 = 5.011268\ \mathrm{u}.

Step 3 — mass defect.

Δm=5.030151−5.011268=0.018883 u>0;\Delta m = 5.030151 - 5.011268 = 0.018883\ \mathrm{u} > 0;

the mass decreases, so energy is released.

Step 4 — energy.

E=Δmc2=0.018883×931.5 MeV≈17.6 MeV.E = \Delta m c^{2} = 0.018883 \times 931.5\ \mathrm{MeV} \approx 17.6\ \mathrm{MeV}.

Answer: about 17.6 MeV17.6\ \mathrm{MeV} per reaction, carried mainly by the neutron and the helium nucleus as kinetic energy.

Practice

Text

Goal: test the conservation laws on real reaction data without any radiation hazard.

  1. Open a nuclear reaction or fission simulation (for example the PhET Nuclear Fission simulation, or any decay-chain simulator available offline). All observation happens on screen; never handle radioactive sources in this lesson.
  2. For each event the simulation shows, record the initial nuclide(s) and the final nuclide(s) in a two-column table with their ZZ and AA.
  3. Check that ∑Z\sum Z and ∑A\sum A are equal before and after the event. If they are not, the event is impossible — state which law is violated.
  4. Repeat for five different events, including at least one beta decay, one alpha decay, and one neutron-induced fission.
  5. For each event, write one sentence saying which conservation check was the most useful.

Visual reference

Purpose

To make the ZZ and AA bookkeeping visible and to show where the mass defect goes in an energy-releasing reaction.

Representation

A labeled sketch of a fission event: 235U^{235}\mathrm{U} absorbs a neutron and splits into two fragments and three neutrons, with each nuclide tagged by its AA and ZZ; below the sketch a balance table lists ∑A\sum A and ∑Z\sum Z for reactants and products, and a second row shows the total rest mass shrinking by Δm\Delta m, with an arrow labeled E=Δmc2E = \Delta m c^{2} pointing to the kinetic energy of the fragments.

Real-world examples

Ionization smoke detector in the kitchen

Scenario

Above the stove in the kitchen there is an ionization smoke detector. Its chamber holds about 33 kBq33\ \text{kBq} (roughly 0.9 μCi0.9\ \mu\text{Ci}) of americium-241. The 95241Am^{241}_{95}\text{Am} nucleus emits an α\alpha particle 24He^{4}_{2}\text{He} with an energy of 5.49 MeV5.49\ \text{MeV} and turns into neptunium-237; the half-life of americium-241 is 432432 years.

Connection

The reaction 95241Am→93237Np+24He^{241}_{95}\text{Am} \to {}^{237}_{93}\text{Np} + {}^{4}_{2}\text{He} shows both conservation rules of this concept. The nucleon number is the same before and after: 241=237+4241 = 237 + 4. The electric charge is also conserved: 95=93+295 = 93 + 2. The emitted α\alpha particles ionize the air between the electrodes and keep a small current flowing; smoke absorbs them, the current drops and the alarm sounds.

A 1000 MW reactor: balancing the fission equation

Scenario

One fission channel in a power reactor is written as 01n+92235U→56141Ba+3692Kr+3 01n^{1}_{0}\text{n} + {}^{235}_{92}\text{U} \to {}^{141}_{56}\text{Ba} + {}^{92}_{36}\text{Kr} + 3\,{}^{1}_{0}\text{n}. A unit of such a power plant feeds 1000 MW1000\ \text{MW} of electric power into the grid, which is enough for about a million flats. Every such fission releases about 200 MeV≈3.2×10−11 J200\ \text{MeV} \approx 3.2\times 10^{-11}\ \text{J}.

Connection

Both conservation laws are at work here. Charge: on the left 92+092 + 0, on the right 56+36+056 + 36 + 0, and 92=56+3692 = 56 + 36. Nucleon number: 1+235=141+92+3⋅1=2361 + 235 = 141 + 92 + 3 \cdot 1 = 236. From the energy of one fission it follows that for 3000 MW3000\ \text{MW} of thermal power the reactor must sustain about 3000×106/3.2×10−11≈10203000\times 10^{6} / 3.2\times 10^{-11} \approx 10^{20} fissions per second — the balanced equation is what gives this estimate.

The Sun's fusion furnace and the weather on Earth

Scenario

Every second the Sun turns about 600600 million tonnes of hydrogen into helium and radiates 3.8×1026 W3.8\times 10^{26}\ \text{W}. The net result of the proton-proton chain is 4 11H→24He+2 e++2 νe4\,{}^{1}_{1}\text{H} \to {}^{4}_{2}\text{He} + 2\,e^{+} + 2\,\nu_e, and 26.7 MeV26.7\ \text{MeV} is released per helium nucleus. So about 8.9×10378.9\times 10^{37} such chains run every second, and this heat reaches us as light and as weather.

Connection

Balancing the reaction gives three checks of this concept. Nucleon number: 4=44 = 4. Electric charge: 4=2+24 = 2 + 2. Lepton number: 0=−2+20 = -2 + 2, because the positrons contribute −2-2 and the neutrinos +2+2. The positrons then annihilate with electrons and add energy, while the neutrinos carry theirs out of the Sun almost without interacting.