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metallic conduction and resistance-temperature dependence

Learning objectives

  • Outcome

    Explain the mechanism of conduction in a metal: describe the role of free electrons and collisions with lattice ions in producing resistance.

  • Outcome

    Apply the formula R=R0(1+α ΔT)R = R_0(1+\alpha\,\Delta T) to calculate the resistance of a metal at a given temperature.

  • Outcome

    Determine the temperature coefficient α\alpha from two measurements of RR and TT and state the limits of the linear model.

Understand the idea

Metallic conduction and the temperature dependence of resistance

Text

In a metal some valence electrons are shared by the whole crystal: they form a free-electron gas that can move through the sample. Under an electric field EE the electrons acquire a drift velocity vdv_d, and the current is I=neAvdI = n e A v_d. Resistance appears because electrons collide with the vibrating lattice ions, and each collision disrupts the directed motion. When the metal is heated, the amplitude of the thermal vibrations grows, collisions become more frequent, the mean free time τ\tau decreases, and the resistivity ρ\rho increases. Over a moderate temperature range this dependence is nearly linear: ρ=ρ0(1+α ΔT),ΔT=T−T0.\rho = \rho_0(1+\alpha\,\Delta T), \qquad \Delta T = T - T_0. Because R=ρL/AR = \rho L / A for a conductor of constant cross-section, the resistance obeys the same law: R=R0(1+α ΔT).R = R_0(1+\alpha\,\Delta T). Here ρ0\rho_0 and R0R_0 refer to the initial temperature T0T_0, and α\alpha is the temperature coefficient of resistance; for metals α>0\alpha > 0 and is of order 10−3 K−110^{-3}\ \text{K}^{-1}. The formula is used together with Ohm's law for a section of a circuit, which links the measured II and UU to the resistance through R=U/IR = U/I.

Worked examples

Direct

Problem

A copper wire has resistance R0=10.0 ΩR_0 = 10.0\ \Omega at T0=20 ∘CT_0 = 20\ ^\circ\text{C}. The temperature coefficient of copper is α=3.9×10−3 K−1\alpha = 3.9\times10^{-3}\ \text{K}^{-1}. What is the resistance of the wire at 80 ∘C80\ ^\circ\text{C}?

Solution

The temperature change is ΔT=80−20=60 K\Delta T = 80 - 20 = 60\ \text{K}. Substitute into the linear law: R=R0(1+α ΔT)=10.0 (1+3.9×10−3⋅60).R = R_0(1+\alpha\,\Delta T) = 10.0\,(1 + 3.9\times10^{-3}\cdot 60). Evaluate the product: 3.9×10−3⋅60=0.2343.9\times10^{-3}\cdot 60 = 0.234. Then R=10.0⋅1.234=12.34 Ω≈12.3 ΩR = 10.0\cdot 1.234 = 12.34\ \Omega \approx 12.3\ \Omega. The resistance increased by about 23 %.

Application

Problem

The filament of a lamp is made of tungsten (α≈4.5×10−3 K−1\alpha \approx 4.5\times10^{-3}\ \text{K}^{-1}). At room temperature 20 ∘C20\ ^\circ\text{C} its resistance is R0=20 ΩR_0 = 20\ \Omega, and in operating mode R=240 ΩR = 240\ \Omega. Estimate the temperature of the filament.

Solution

The resistance ratio is RR0=24020=12\dfrac{R}{R_0} = \dfrac{240}{20} = 12. From R=R0(1+α ΔT)R = R_0(1+\alpha\,\Delta T) we get 12=1+α ΔT⇒ΔT=12−14.5×10−3≈2.44×103 K.12 = 1+\alpha\,\Delta T \quad\Rightarrow\quad \Delta T = \frac{12-1}{4.5\times10^{-3}} \approx 2.44\times10^{3}\ \text{K}. The absolute temperature is T=T0+ΔT≈293+2444≈2.74×103 KT = T_0 + \Delta T \approx 293 + 2444 \approx 2.74\times10^{3}\ \text{K} (about 2.5×103 ∘C2.5\times10^{3}\ ^\circ\text{C}). The estimate gives the correct order of magnitude; the small discrepancy arises because α\alpha of tungsten decreases slightly at such high temperatures.

Transfer

Problem

A student measures the resistance of a metal resistor: at 0 ∘C0\ ^\circ\text{C} it is R1=4.00 ΩR_1 = 4.00\ \Omega, and at 100 ∘C100\ ^\circ\text{C} it is R2=5.56 ΩR_2 = 5.56\ \Omega. (a) Find α\alpha from these two points. (b) Predict RR at 400 ∘C400\ ^\circ\text{C} within the linear model. (c) Give one reason why the prediction may be inaccurate.

Solution

(a) Here ΔT=100 K\Delta T = 100\ \text{K} and the resistance increment is R2−R1=1.56 ΩR_2 - R_1 = 1.56\ \Omega. From R2−R1=R1 α ΔTR_2 - R_1 = R_1\,\alpha\,\Delta T we obtain α=1.564.00⋅100=3.9×10−3 K−1.\alpha = \frac{1.56}{4.00\cdot 100} = 3.9\times10^{-3}\ \text{K}^{-1}. (b) For ΔT=400 K\Delta T = 400\ \text{K}: R=4.00 (1+3.9×10−3⋅400)=4.00⋅2.56=10.24 Ω.R = 4.00\,(1 + 3.9\times10^{-3}\cdot 400) = 4.00\cdot 2.56 = 10.24\ \Omega. (c) The coefficient α\alpha itself depends on temperature, so over a large interval ΔT\Delta T the true dependence R(T)R(T) is slightly nonlinear; in addition, surface oxidation and poor thermal contact of the resistor mean that its real temperature differs from the thermometer reading.

Practice

Text

Self-check in a simulation (safe). Use a virtual laboratory — for example, PhET "Resistance in a Wire" or a circuit simulator with a thermistor.

  1. Set the length and cross-sectional area of the wire and switch on the ρ(T)\rho(T) model.
  2. Record the resistance RR at five temperatures, including T0=20 ∘CT_0 = 20\ ^\circ\text{C}.
  3. Plot R(T)R(T) and check that the points fall on a straight line; find α\alpha from the slope: α=R−R0R0 ΔT\alpha = \dfrac{R-R_0}{R_0\,\Delta T}.
  4. Compare the value of α\alpha you obtained with the tabulated value for the chosen metal and explain the difference.

Safety rules. Never test the temperature dependence by connecting an incandescent lamp to a 220 V mains supply. For a home measurement use battery power and a multimeter only; measure the cold filament resistance when the lamp is switched off and completely cooled.

Visual reference

Purpose

Show that the resistance of a metal grows almost linearly with temperature, and link the slope of the graph to the temperature coefficient α\alpha and to the mechanism of electron collisions with lattice ions.

Representation

A graph of R(T)R(T): a straight line passing through the point (T0,R0)(T_0,R_0) with slope αR0\alpha R_0; the same figure marks the slope ΔRΔT\dfrac{\Delta R}{\Delta T}. Beside it, a sketch shows ions at the lattice sites and free electrons; arrows indicate the electron drift, and two panels with small and large amplitudes of ion vibration illustrate why heating makes collisions more frequent.

Real-world examples

Incandescent lamp: why a cold filament draws a larger current

Scenario

A 60 W60\ \text{W} lamp is connected to a 230 V230\ \text{V} mains supply. In steady operation the tungsten filament (α≈4.5⋅10−3 K−1\alpha \approx 4.5\cdot10^{-3}\ \text{K}^{-1}) is at about 2700 ∘C2700\ ^\circ\text{C}, its resistance is Rhot=U2/P=(230 V)2/60 W≈882 ΩR_\text{hot} = U^2/P = (230\ \text{V})^2/60\ \text{W} \approx 882\ \Omega, and the current is I=P/U≈0.26 AI = P/U \approx 0.26\ \text{A}. At 20 ∘C20\ ^\circ\text{C} the temperature rise is ΔT≈2680 K\Delta T \approx 2680\ \text{K}, so Rcold=Rhot/(1+αΔT)≈882/13≈68 ΩR_\text{cold} = R_\text{hot}/(1+\alpha\Delta T) \approx 882/13 \approx 68\ \Omega, and at switch-on the current reaches 230 V/68 Ω≈3.4 A230\ \text{V}/68\ \Omega \approx 3.4\ \text{A}, about 13 times the steady value.

Connection

The filament is a metal: the current is carried by free electrons accelerated by the field, which collide with the vibrating lattice ions. On heating, the ions vibrate with larger amplitude, scattering becomes stronger, and the resistivity grows as ρ=ρ0(1+αΔT)\rho = \rho_0(1+\alpha \Delta T). For a fixed geometry R=ρL/AR=\rho L/A rises by the same factor — this is what links the measured cold and hot currents to the temperature coefficient α\alpha.

Car starter cable: copper heating under current

Scenario

A 12 V12\ \text{V} battery feeds a starter through a copper cable of length 1.2 m1.2\ \text{m} and cross-section 25 mm225\ \text{mm}^2. At 20 ∘C20\ ^\circ\text{C} the resistivity of copper is ρ0=1.7⋅10−8 Ω⋅m\rho_0 = 1.7\cdot10^{-8}\ \Omega\cdot\text{m}, so R=ρ0L/A≈1.7⋅10−8⋅1.2/(25⋅10−6)≈8.2⋅10−4 Ω≈0.8 mΩR = \rho_0 L/A \approx 1.7\cdot10^{-8}\cdot1.2/(25\cdot10^{-6}) \approx 8.2\cdot10^{-4}\ \Omega \approx 0.8\ \text{m}\Omega. At a current of 150 A150\ \text{A} the voltage drop along the cable is IR≈0.12 VIR \approx 0.12\ \text{V} and the heating power is I2R≈18 WI^2R \approx 18\ \text{W}. Within a few seconds the copper warms to 60 ∘C60\ ^\circ\text{C} (ΔT=40 K\Delta T = 40\ \text{K}, α=3.9⋅10−3 K−1\alpha = 3.9\cdot10^{-3}\ \text{K}^{-1}): the resistance rises by about 16%16\% to 0.95 mΩ0.95\ \text{m}\Omega, and the voltage drop becomes 0.14 V0.14\ \text{V}.

Connection

The cable is a metallic part of the circuit, so its resistance enters Ohm's law for a complete circuit: the current is set by the sum of the resistances. The resistivity of copper depends on temperature as ρ=ρ0(1+αΔT)\rho = \rho_0(1+\alpha\Delta T), and R=ρL/AR=\rho L/A; therefore as it warms the resistance grows and the current through the starter decreases. At the same time the power I2RI^2R is released, which heats the cable further — a feedback loop.

Toaster: nichrome with a small temperature coefficient

Scenario

An 800 W800\ \text{W} toaster runs on 230 V230\ \text{V}; in steady operation at about 500 ∘C500\ ^\circ\text{C} its resistance is Rhot=U2/P=(230 V)2/800 W≈66 ΩR_\text{hot} = U^2/P = (230\ \text{V})^2/800\ \text{W} \approx 66\ \Omega, and the current is I=P/U≈3.5 AI = P/U \approx 3.5\ \text{A}. For nichrome α≈4⋅10−4 K−1\alpha \approx 4\cdot10^{-4}\ \text{K}^{-1}, so with ΔT=480 K\Delta T = 480\ \text{K} the factor 1+αΔT≈1.191+\alpha\Delta T \approx 1.19. Hence at 20 ∘C20\ ^\circ\text{C} the resistance is Rcold≈66/1.19≈55 ΩR_\text{cold} \approx 66/1.19 \approx 55\ \Omega, and the switch-on current 230 V/55 Ω≈4.1 A230\ \text{V}/55\ \Omega \approx 4.1\ \text{A} is only 19%19\% above the steady value.

Connection

The mechanism is the same: conduction electrons collide with lattice ions, and a higher temperature increases scattering. But in the disordered alloy nichrome the extra scattering from thermal vibrations is only a small fraction, so α\alpha is small and the resistance changes little with temperature. Through Ohm's law for a complete circuit this means an almost constant current I=ε/(R+r)I = \varepsilon/(R+r) and power P=I2RP = I^2R, which is what a heating appliance needs.