Learning objectives
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Outcome
Classify a material as diamagnetic, paramagnetic, or ferromagnetic from the sign and order of magnitude of its magnetic susceptibility or relative permeability .
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Outcome
Explain the microscopic mechanism (induced orbital currents, thermal randomization of permanent moments, or domain alignment) that produces each material type's response to an applied field .
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Outcome
Compute the field inside a material with and , and predict how a core changes the field of a coil.
Understand the idea
Dia-, para- and ferromagnetic materials
Text
An applied magnetic field , produced by currents or permanent magnets, acts on the electrons inside a material; the total field inside is the superposition where is the field created by the material's own atomic currents and magnetic moments.
Diamagnetic materials have no permanent atomic moments: the applied field induces orbital currents whose magnetic moments point opposite to , so , , and is slightly less than 1; such a sample is weakly pushed out of a region of strong field.
Paramagnetic materials have permanent atomic moments that are randomized by thermal motion; the field partially aligns them along , giving a small positive susceptibility and slightly greater than 1.
Ferromagnetic materials — iron, cobalt, nickel — have strong quantum exchange coupling that locks neighbouring moments into domains; an applied field aligns the domains, producing of order –, together with saturation and hysteresis.
Because the material's field adds to the applied field by superposition, a ferromagnetic core can raise inside a coil by hundreds or thousands of times, while a diamagnetic sample slightly reduces it.
Worked examples
Direct
Problem
Use the value of the magnetic susceptibility to identify the type of material: (a) ; (b) ; (c) . For each case state the sign, the order of magnitude, and name the material class.
Solution
Compute and compare it with 1.
- (a) , : induced moments oppose — a diamagnet, .
- (b) but very small (): permanent moments are only partially aligned by the field — a paramagnet, .
- (c) and large (): moments order in domains — a ferromagnet, ; this response is nonlinear and can saturate.
Application
Problem
A paramagnetic sample sits in a uniform field T; its susceptibility is . Find the field strength in the sample, the magnetization , and the total field inside the sample.
Solution
The applied field fixes the field strength:
Magnetization:
Field created by the material: T.
Total field by superposition:
Conclusion: the paramagnetic sample adds only to the applied field, so its contribution is invisible without a sensitive instrument.
Transfer
Problem
A solenoid without a core produces a field mT. An iron core is inserted. (a) Below saturation the core has relative permeability ; find the field inside. (b) The current is doubled ( mT) and the core saturates, where drops to ; find the new field and compare it with the linear prediction from part (a).
Solution
(a) The core's field adds to the applied field by superposition, which gives :
(b) With doubled current the applied field is mT, but the permeability is no longer the same:
The linear prediction would be T. The actual increase is only , that is instead of .
Reason: at saturation the permeability drops, so grows sublinearly with : had stayed at , the field would have doubled, whereas the actual increase is only . The field of the material itself still grows — from T to T, an increase of about — because the applied field still rotates more domains into alignment. However, the growth of slows as the magnetization approaches saturation, and beyond saturation the further increase of comes mainly from the direct growth of the applied field rather than from the material's contribution; hence stops being constant and the relation between and becomes nonlinear.
Practice
Text
Run the safe self-study experiment in a simulation (for example, PhET "Magnets and Electromagnets" or "Magnet and Compass"), not with strong neodymium magnets near electronics, pacemakers, or bank cards.
- Create a uniform applied field and record its value.
- Place three virtual samples in the field one at a time: diamagnetic (), paramagnetic (), and ferromagnetic (). For each, record the directions of , , and the total field .
- Plot inside the sample against for the ferromagnetic case, raising the field up to saturation; mark the point where the curve departs from a straight line.
- Write a 3–4 sentence conclusion: how the sign of and the saturation effect follow from superposition of fields.
Visual reference
Purpose
Compare how three classes of material respond to the same applied field , and show why superposition yields different total fields inside the matter.
Representation
A three-column sketch labelled "diamagnet", "paramagnet", "ferromagnet".
Top row: identical arrows of the applied field .
Middle row: atomic magnetic moments — induced and antiparallel to (dia); partially aligned along (para); locked into domains and almost fully aligned (ferro).
Bottom row: an arrow for and a resultant arrow for , labelled , , .
Inset on the right: a graph of versus — almost a straight line for the dia- and paramagnet, and a curve that flattens into a plateau (saturation) for the ferromagnet; next to the plateau the note reads decreases, is not constant.
Real-world examples
Fridge magnet on a steel door
Scenario
A neodymium NdFeB magnet of mass , size , with a surface induction , holds a stack of notes on a steel refrigerator door. The door is mild low-carbon steel with relative permeability –; pure iron saturates at .
Connection
This is plain ferromagnetism. The external field rotates whole domains in the steel — regions where the atomic moments already point the same way — so the induction inside the door rises into the tesla range instead of staying at the air value . At (the Curie point of iron) the domain order disappears and the steel stops attracting. Complete domain alignment gives saturation: a thicker magnet no longer increases the holding force.
Liquid oxygen between the poles of an electromagnet
Scenario
In a lecture demonstration a glass tube of liquid oxygen at is brought into a gap between the poles of an electromagnet with . The pale-blue liquid is pulled into the region of strongest field, hangs there, and stays until it boils away at .
Connection
This is paramagnetism. The molecule carries a permanent magnetic moment of , and the field tries to turn these moments along itself, but thermal motion at opposes this. The magnetic susceptibility is therefore small and positive: , i.e. . The magnetization is proportional to the field (Curie law ), so switching the magnet off removes the effect instantly, and warming weakens it.
Graphite levitation above strong neodymium magnets
Scenario
A plate of pyrolytic graphite , mass about (density ), floats steadily – above a stack of neodymium magnets with a surface induction and a field gradient of a few hundred .
Connection
This is diamagnetism. The external field induces circular currents in the graphite atoms, and by Lenz's rule their magnetic moment points against the field: . Such a material is pushed towards a weaker field. Levitation occurs when the magnetic force balances the weight: , which is exactly what the required and gradient provide. The same diamagnetism exists in water () and in any tissue.