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dia para and ferromagnetic materials

Learning objectives

  • Outcome

    Classify a material as diamagnetic, paramagnetic, or ferromagnetic from the sign and order of magnitude of its magnetic susceptibility χ\chi or relative permeability μr\mu_r.

  • Outcome

    Explain the microscopic mechanism (induced orbital currents, thermal randomization of permanent moments, or domain alignment) that produces each material type's response to an applied field B⃗0\vec B_0.

  • Outcome

    Compute the field inside a material with B⃗=B⃗0+B⃗mat\vec B = \vec B_0 + \vec B_{\text{mat}} and μr=1+χ\mu_r = 1 + \chi, and predict how a core changes the field of a coil.

Understand the idea

Dia-, para- and ferromagnetic materials

Text

An applied magnetic field B⃗0\vec B_0, produced by currents or permanent magnets, acts on the electrons inside a material; the total field inside is the superposition B⃗=B⃗0+B⃗mat,\vec B = \vec B_0 + \vec B_{\text{mat}}, where B⃗mat\vec B_{\text{mat}} is the field created by the material's own atomic currents and magnetic moments.

Diamagnetic materials have no permanent atomic moments: the applied field induces orbital currents whose magnetic moments point opposite to B⃗0\vec B_0, so χ<0\chi<0, ∣χ∣∼10−5|\chi|\sim10^{-5}, and μr=BB0=1+χ\mu_r = \dfrac{B}{B_0} = 1+\chi is slightly less than 1; such a sample is weakly pushed out of a region of strong field.

Paramagnetic materials have permanent atomic moments that are randomized by thermal motion; the field partially aligns them along B⃗0\vec B_0, giving a small positive susceptibility χ∼10−5…10−3\chi\sim10^{-5}\ldots10^{-3} and μr\mu_r slightly greater than 1.

Ferromagnetic materials — iron, cobalt, nickel — have strong quantum exchange coupling that locks neighbouring moments into domains; an applied field aligns the domains, producing χ\chi of order 10210^2–10610^6, together with saturation and hysteresis.

Because the material's field adds to the applied field by superposition, a ferromagnetic core can raise BB inside a coil by hundreds or thousands of times, while a diamagnetic sample slightly reduces it.

Worked examples

Direct

Problem

Use the value of the magnetic susceptibility χ\chi to identify the type of material: (a) χ=−9.0⋅10−6\chi = -9.0\cdot10^{-6}; (b) χ=+2.2⋅10−4\chi = +2.2\cdot10^{-4}; (c) χ=+5.0⋅103\chi = +5.0\cdot10^{3}. For each case state the sign, the order of magnitude, and name the material class.

Solution

Compute μr=1+χ\mu_r = 1+\chi and compare it with 1.

  • (a) χ<0\chi<0, ∣χ∣∼10−5|\chi|\sim10^{-5}: induced moments oppose B⃗0\vec B_0 — a diamagnet, μr=1−9.0⋅10−6≈0.999991\mu_r = 1-9.0\cdot10^{-6} \approx 0.999991.
  • (b) χ>0\chi>0 but very small (∼10−4\sim10^{-4}): permanent moments are only partially aligned by the field — a paramagnet, μr=1+2.2⋅10−4≈1.00022\mu_r = 1+2.2\cdot10^{-4} \approx 1.00022.
  • (c) χ>0\chi>0 and large (∼103\sim10^{3}): moments order in domains — a ferromagnet, μr=1+5.0⋅103≈5000\mu_r = 1+5.0\cdot10^{3} \approx 5000; this response is nonlinear and can saturate.

Application

Problem

A paramagnetic sample sits in a uniform field B0=0.50B_0 = 0.50 T; its susceptibility is χ=3.0⋅10−4\chi = 3.0\cdot10^{-4}. Find the field strength HH in the sample, the magnetization MM, and the total field BB inside the sample.

Solution

The applied field fixes the field strength: H=B0μ0=0.504π⋅10−7≈3.98⋅105 A/m.H = \frac{B_0}{\mu_0} = \frac{0.50}{4\pi\cdot10^{-7}} \approx 3.98\cdot10^{5}\ \text{A/m}.

Magnetization: M=χH=3.0⋅10−4⋅3.98⋅105≈1.2⋅102 A/m.M = \chi H = 3.0\cdot10^{-4}\cdot3.98\cdot10^{5} \approx 1.2\cdot10^{2}\ \text{A/m}.

Field created by the material: Bmat=μ0M=χB0=3.0⋅10−4⋅0.50=1.5⋅10−4B_{\text{mat}} = \mu_0 M = \chi B_0 = 3.0\cdot10^{-4}\cdot0.50 = 1.5\cdot10^{-4} T.

Total field by superposition: B=μ0(H+M)=B0(1+χ)=0.50⋅1.0003≈0.50015 T.B = \mu_0(H+M) = B_0(1+\chi) = 0.50\cdot1.0003 \approx 0.50015\ \text{T}.

Conclusion: the paramagnetic sample adds only ∼0.03%\sim0.03\% to the applied field, so its contribution is invisible without a sensitive instrument.

Transfer

Problem

A solenoid without a core produces a field B0=1.0B_0 = 1.0 mT. An iron core is inserted. (a) Below saturation the core has relative permeability μr=1500\mu_r = 1500; find the field BB inside. (b) The current is doubled (B0=2.0B_0 = 2.0 mT) and the core saturates, where μr\mu_r drops to 900900; find the new field and compare it with the linear prediction 2B2B from part (a).

Solution

(a) The core's field adds to the applied field by superposition, which gives B=μrB0B = \mu_r B_0: Ba=μrB0=1500⋅1.0⋅10−3=1.5 T.B_a = \mu_r B_0 = 1500\cdot1.0\cdot10^{-3} = 1.5\ \text{T}.

(b) With doubled current the applied field is B0=2.0B_0 = 2.0 mT, but the permeability is no longer the same: Bb=900⋅2.0⋅10−3=1.8 T.B_b = 900\cdot2.0\cdot10^{-3} = 1.8\ \text{T}.

The linear prediction would be 2Ba=3.02B_a = 3.0 T. The actual increase is only 1.8/1.5=1.21.8/1.5 = 1.2, that is +20%+20\% instead of +100%+100\%.

Reason: at saturation the permeability drops, so BB grows sublinearly with B0B_0: had μr\mu_r stayed at 15001500, the field would have doubled, whereas the actual increase is only +20%+20\%. The field of the material itself still grows — from Bmat,a=1.5−0.001=1.499B_{\text{mat},a} = 1.5 - 0.001 = 1.499 T to Bmat,b=1.8−0.002=1.798B_{\text{mat},b} = 1.8 - 0.002 = 1.798 T, an increase of about 20%20\% — because the applied field still rotates more domains into alignment. However, the growth of BmatB_{\text{mat}} slows as the magnetization MM approaches saturation, and beyond saturation the further increase of BB comes mainly from the direct growth of the applied field B0B_0 rather than from the material's contribution; hence μr\mu_r stops being constant and the relation between BB and B0B_0 becomes nonlinear.

Practice

Text

Run the safe self-study experiment in a simulation (for example, PhET "Magnets and Electromagnets" or "Magnet and Compass"), not with strong neodymium magnets near electronics, pacemakers, or bank cards.

  1. Create a uniform applied field B⃗0\vec B_0 and record its value.
  2. Place three virtual samples in the field one at a time: diamagnetic (χ=−1⋅10−5\chi = -1\cdot10^{-5}), paramagnetic (χ=+1⋅10−4\chi = +1\cdot10^{-4}), and ferromagnetic (μr=1000\mu_r = 1000). For each, record the directions of B⃗0\vec B_0, B⃗mat\vec B_{\text{mat}}, and the total field B⃗\vec B.
  3. Plot BB inside the sample against B0B_0 for the ferromagnetic case, raising the field up to saturation; mark the point where the curve departs from a straight line.
  4. Write a 3–4 sentence conclusion: how the sign of χ\chi and the saturation effect follow from superposition of fields.

Visual reference

Purpose

Compare how three classes of material respond to the same applied field B⃗0\vec B_0, and show why superposition yields different total fields B⃗\vec B inside the matter.

Representation

A three-column sketch labelled "diamagnet", "paramagnet", "ferromagnet".

Top row: identical arrows of the applied field B⃗0\vec B_0.

Middle row: atomic magnetic moments — induced and antiparallel to B⃗0\vec B_0 (dia); partially aligned along B⃗0\vec B_0 (para); locked into domains and almost fully aligned (ferro).

Bottom row: an arrow for B⃗mat\vec B_{\text{mat}} and a resultant arrow for B⃗=B⃗0+B⃗mat\vec B = \vec B_0 + \vec B_{\text{mat}}, labelled μr<1\mu_r < 1, μr≳1\mu_r \gtrsim 1, μr≫1\mu_r \gg 1.

Inset on the right: a graph of BB versus B0B_0 — almost a straight line for the dia- and paramagnet, and a curve that flattens into a plateau (saturation) for the ferromagnet; next to the plateau the note reads χ→\chi \to decreases, μr\mu_r is not constant.

Real-world examples

Fridge magnet on a steel door

Scenario

A neodymium NdFeB magnet of mass 5 g5\ \mathrm{g}, size 20×10×3 mm20\times10\times3\ \mathrm{mm}, with a surface induction B0≈0.4 TB_0\approx0.4\ \mathrm{T}, holds a 300 g300\ \mathrm{g} stack of notes on a steel refrigerator door. The door is mild low-carbon steel with relative permeability μr≈1000\mu_r\approx1000–50005000; pure iron saturates at Bs≈2 TB_s\approx2\ \mathrm{T}.

Connection

This is plain ferromagnetism. The external field B0=0.4 TB_0=0.4\ \mathrm{T} rotates whole domains in the steel — regions where the atomic moments already point the same way — so the induction inside the door B=μ0(H+M)B=\mu_0(H+M) rises into the tesla range instead of staying at the air value B0B_0. At TC≈1043 KT_C\approx1043\ \mathrm{K} (the Curie point of iron) the domain order disappears and the steel stops attracting. Complete domain alignment gives saturation: a thicker magnet no longer increases the holding force.

Liquid oxygen between the poles of an electromagnet

Scenario

In a lecture demonstration a glass tube of liquid oxygen at 90 K90\ \mathrm{K} is brought into a 30 mm30\ \mathrm{mm} gap between the poles of an electromagnet with B=0.5 TB=0.5\ \mathrm{T}. The pale-blue liquid is pulled into the region of strongest field, hangs there, and stays until it boils away at 90.2 K90.2\ \mathrm{K}.

Connection

This is paramagnetism. The O2\mathrm{O_2} molecule carries a permanent magnetic moment of 2 μB2\ \mu_\mathrm{B}, and the field tries to turn these moments along itself, but thermal motion at 90 K90\ \mathrm{K} opposes this. The magnetic susceptibility is therefore small and positive: χ≈3.4×10−3\chi\approx3.4\times10^{-3}, i.e. μr=1+χ≈1.003\mu_r=1+\chi\approx1.003. The magnetization is proportional to the field (Curie law M∝B/TM\propto B/T), so switching the magnet off removes the effect instantly, and warming weakens it.

Graphite levitation above strong neodymium magnets

Scenario

A plate of pyrolytic graphite 10×10×1 mm10\times10\times1\ \mathrm{mm}, mass about 0.22 g0.22\ \mathrm{g} (density 2.2 g/cm32.2\ \mathrm{g/cm^3}), floats steadily 55–10 mm10\ \mathrm{mm} above a stack of neodymium magnets with a surface induction B≈0.5 TB\approx0.5\ \mathrm{T} and a field gradient of a few hundred T/m\mathrm{T/m}.

Connection

This is diamagnetism. The external field induces circular currents in the graphite atoms, and by Lenz's rule their magnetic moment points against the field: χ≈−1.6×10−4\chi\approx-1.6\times10^{-4}. Such a material is pushed towards a weaker field. Levitation occurs when the magnetic force balances the weight: B dBdz≥μ0ρg∣χ∣≈1.7×102 T2/mB\,\dfrac{dB}{dz}\ge\dfrac{\mu_0\rho g}{|\chi|}\approx1.7\times10^{2}\ \mathrm{T^2/m}, which is exactly what the required BB and gradient provide. The same diamagnetism exists in water (χ=−9×10−6\chi=-9\times10^{-6}) and in any tissue.